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Why does water expand when it freezes?
According to Dr. Arnold G. Gill (Astrophysician, Malaspina University-College, British Columbia, Canada),: "The expansion has to do with the peculiar molecular structure of water. Within the limits imposed by this keyboard, a water molecule looks like (Left diagram). Each of the hydrogen atoms weakly attracts nearby oxygen atoms, so water binds together. When liquid, the binding is weak, but when solid, the bonds become quite strong, and constrain how the molecules may arrange themselves as a crystal. In its liquid state, the molecules are free to roam around wherever they wish. However, in its frozen state, the water molecules form a hexagon (six-sided figure), giving the beautiful six-sided snowflakes that we are all familiar with. In this state, the molecules line up approximately like the sketch (right diagram) below with the lines showing the molecular bonds holding the molecules in place. Notice that the center is empty! In its liquid form, with the molecules moving about freely, you will find an H2O molecule in the center of such a structure, but not in its solid state. So, a given amount of water will use up more room as ice than as a liquid, because of the empty space that appears as it freezes. Thus, ice is less dense and it floats. (And in case you are wondering, the center is EMPTY; it is NOT filled with air. Air bubbles are extra effects that help to float ice, but air bubbles are not needed to get ice to float.) You've probably heard that 90% of an iceberg is under water. This suggests that the density of ice is about 10% (1/10) less than that of water. Yet, from the simple diagram above, there are 6 water molecules where before there were 7 - a difference of about 14% (1/7). Why the discrepancy? While frozen water has a unique crystal structure, it also acts like every other substance in the world - it contracts when it cools. That is, the average distance between adjacent water molecules still decreases when water freezes (in the diagram, the lines connecting the molecules get shorter). The net result is that the group of molecules shrinks, but the center remains empty - or 1/7 shrinks to about 1/10."
Water molecule in liquid state |
Water molecule in solid state |
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Groundwater levels may have a long term trend of rising or falling
Water will flow faster in a pipe that is about 80 percent capacity than it will in one that is near 100% capacity under gravity flow.
Water speed in a pipe will vary with the texture of the pipe, diameter, slope, and material.

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